2024
Variability in Constituents of E-Cigarette Products Containing Nicotine Analogues
Erythropel H, Jabba S, Silinski P, Anastas P, Krishnan-Sarin S, Zimmerman J, Jordt S. Variability in Constituents of E-Cigarette Products Containing Nicotine Analogues. JAMA 2024, 332: 753-755. PMID: 39110443, PMCID: PMC11307159, DOI: 10.1001/jama.2024.12408.Peer-Reviewed Original ResearchRoom temperature catalytic upgrading of unpurified lignin depolymerization oil into bisphenols and butene-2
Subbotina E, Souza L, Zimmerman J, Anastas P. Room temperature catalytic upgrading of unpurified lignin depolymerization oil into bisphenols and butene-2. Nature Communications 2024, 15: 5892. PMID: 39003256, PMCID: PMC11246530, DOI: 10.1038/s41467-024-49812-x.Peer-Reviewed Original ResearchButene-2Bio-based carbon contentSource of renewable aromaticsGlass transition temperatureSynthetic utilityOlefin metathesisReductive catalytic fractionationBio-based carbonCatalyst loadingTarget monomersMild conditionsHydrogen pressureThermal stabilityRenewable aromaticsLoss of functionTransition temperatureCatalytic fractionationLignin depolymerizationCatalytic upgradingConvert ligninMonomerUpgrading methodsBisphenolHigh temperatureApproaches to the Oxidative Depolymerization of Lignin
Subbotina E, Stahl S, Anastas P, Samec J. Approaches to the Oxidative Depolymerization of Lignin. 2024, 231-263. DOI: 10.1002/9783527839865.ch9.Peer-Reviewed Original ResearchModel compoundsProduction of vanillinAromatic compoundsModel compounds of ligninLignin model compoundsValorization of ligninCompounds of ligninFraction of woodValorize ligninLignin valorizationDepolymerization of ligninPhoto-catalysisOxidative depolymerization of ligninMechanistic discussionIonic liquidsRemove ligninSulfite liquorIndustrial side streamsEutectic solventsOxidation methodLigninOxidative delignificationOxidative depolymerizationNative ligninCompoundsCarbocation Mechanism Revelation of Molecular Iodine-Mediated Dehydrogenative Aromatization of Substituted Cyclic Ketones to Phenols
Jin Y, Petrovic P, Huang S, Banerjee S, Nandy A, Anastas P, Lam J. Carbocation Mechanism Revelation of Molecular Iodine-Mediated Dehydrogenative Aromatization of Substituted Cyclic Ketones to Phenols. The Journal Of Organic Chemistry 2024, 89: 3226-3237. PMID: 38361498, DOI: 10.1021/acs.joc.3c02691.Peer-Reviewed Original ResearchDehydrogenative aromatizationCyclic ketonesDesorption electrospray ionization-mass spectrometryC-H bond activationElectrospray ionization-mass spectrometrySubstrate scope studyUnsaturated cyclic ketonesIonization-mass spectrometryHigh energy barrierProton nuclear magnetic resonanceMass spectrometric analysisBond activationSubstrate scopeDFT calculationsNuclear magnetic resonanceProduct selectivityPhenol etherReaction mechanismCarbocationProduct distributionSpectrometric analysisKetonesWater boiling temperatureAmbient conditionsAromatic precursorsA Historical and Current Look at Chemical Design for Reduced Hazard
Petrovic P, Coish P, Anastas P. A Historical and Current Look at Chemical Design for Reduced Hazard. 2024 DOI: 10.1016/b978-0-443-15742-4.00072-7.Peer-Reviewed Original Research
2021
The Law of the Land: Sustainable Chemistry Innovation
Anastas P. The Law of the Land: Sustainable Chemistry Innovation. ACS Sustainable Chemistry & Engineering 2021, 9: 5250-5251. DOI: 10.1021/acssuschemeng.1c02311.Peer-Reviewed Original Research